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Besides reactive minerals, aggregates may contain other impurities,
such as organic matter, which are harmful to concrete.
Organic matter, such as that derived from decaying vegetation,
is capable of delaying setting and hardening of concrete.
It is more likely to be found in fine than in coarse aggregate
and may be detected by the test set out in NZS 3111, Section
17. In this test, sand in a bottle is inundated in a sodium
hydroxide solution and allowed to stand for 24 hours. The
colour of the liquid above the sample is then compared with
the colour of a standard reference solution. If the colour
of the liquid is lighter than that of the reference solution,
the amount of organic impurities present in the aggregate
is not significant. If the colour of the liquid is darker
than that of the reference solution, the aggregate contains
organic compounds and further tests should be made to determine
if these are harmful. Normally, the strength of concrete made
with the sand is used as a gauge of the harmful effects of
the impurities.
Sugar has a strong retarding effect on the setting and hardening
of concrete. In severe cases of contamination, the resulting
concrete may not set or may fail to gain appreciable strength. AS 2758.1
specifies a maximum limit on the sugar content of aggregate of one part in 10,000 determined in accordance
with AS 1141, Section 35.
Silt, clay and dust may form a coating on aggregate particles,
resulting in weakened bond between the aggregate and the cement
paste. Excessive amounts of these fine materials may also
increase unduly the water demand of the concrete, resulting
in loss of concrete strength and an increase in its permeability.
Cleanness in coarse aggregate can be determined by a test
contained in NZS 3111, Section 13. Similarly the same Standard
in Section 18 has a method of determining clay content.
The presence of certain clay minerals, particularly the montmorilionites,
will cause changes in volume with changing moisture conditions.
Where such volumetric
instability exists, the concrete may deteriorate rapidly with
cycles of wetting and drying. The wet/dry strength-variation
test set out in AS 1141.22 can be used as a guide to the dimensional
stability of the coarse aggregate.
The amount of fine material is determined by washing a sample
of the aggregate over a small sieve. Sections 12 and 13 in
AS 1141 describe this type of test.
Coal, wood and other lightweight materials tend to rise to
the surface during vibration of concrete, especially in pavements
and floors, and produce a very poor surface finish. They also
cause pop-outs and staining on vertical surfaces. The percentage of light particles can be determined by the
test set out in NZS 3111 Section 9. AS 2758.1 specifies a maximum limit on
light particles of 1 % by mass of aggregate (3% for slag aggregate).
There are no limits set by New Zealand Standards but as the
percentage of lightweight particles increases the strength
will decrease, requiring the use of NZS 3111, Section 8 Aggregate Performance in Concrete to determine
an acceptable limit for supply of concrete. Where surface appearance of the concrete is important, the
amount of coal, wood and charcoal should preferably be even
less.
Aggregates, particularly those dredged from the sea, or those
quenched and washed with sea water, may be contaminated by
sea salt which contains a high proportion of chloride ions.
The amount of chlorides in concrete is of major concern because
of its influence on the corrosion of embedded steel. They
also increase shrinkage and reduce the sulphate resistance
of concrete. Table 8 in AS 2758.1 and Clause 6.6 of NZS 3109
specify (in different ways) maximum chloride contents for
concrete as placed. Adoption of the limits specified in the
latter is recommended, ie total chloride of concrete shall
not exceed for:
| Prestressed
concrete |
0.5 kg/m³ |
| Reinforced
concrete
|
| a) Located in moist environment or exposed to chloride |
0.8kg/m³ |
| b) Located
in a dry or protected environment |
1.6kg/m³ |
| Total sulphate content shall not
exceed 5% of the mass of the cement. |
|
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